You're lucky it's ever done anything on that disc. Multi session DVDs aren't supported. Read mode blocks them, verify mode doesn't appear to (I probably forgot) but obviously doesn't work.
It's reading from the wrong places, so verification is pointless on such a disc and for whatever reason, it's trying to read faaaar too much in one go and that's why you've got the error about the user buffer.
Edit: oops not far too much, it's trying to read backwards or something as it hits session 2.